Hydroboration of Methyl Esters of Fatty Acids

Stability of unsaturated methyl esters of fatty acids on surfaces.

The stability of unsaturated methyl esters is greater when they are adsorbed on silica gel than when a glass surface is used. Storage of small samples adsorbed on silica gel may be a convenient addition to conventional methods of protecting labile fats against autoxidation.

Method of Converting Free Fatty Acids to Fatty Acid Methyl Esters

A method for converting free fatty acids in acid oil or acid fat into fatty acid methyl esters is disclosed. The method involves adding a small amount of methanol and an acid catalyst to the acid oil or acid fat and subjecting the mixture to conditions that allow the fatty acid methyl esters to form. A lipid phase containing the fatty acid methyl esters and triglycerides can from and be separat...

Crystallization Behavior of Fatty Acid Methyl Esters

Biodiesel from most agricultural feedstocks has flow properties that are prone to startup and operability problems during cold weather. Biodiesel from soybean oil is generally a mixture of long-chain fatty acid alkyl esters composed of 0.15–0.20 mass fraction saturated esters (melting point [MP] 0 C) mixed with unsaturated esters (MP \ 0 C). This work investigates the crystallization properties...

Esters of Omega-3 Fatty Acids

A Continuous Process for the Conversion of Vegetable Oils into Methyl Esters of Fatty Acids

A continuous process for the transesterification of triglycerides to methyl esters was investigated in a pilot plant. The process was equipped with a motionlerr and a high-shear mixer. The experimental studies explored variations in the mixing intensity, stcichionetry, and catalyst concentration on the overall conversion. The combined as well as individual effect of mixers was examined. The dev...